Product ID:EVEREADY BATTERY LITH-MANG-DIOXIDE
MSDS Date:01/08/1998
FSC:6135
NIIN:01-462-4007
Status Code:A
MSDS Number: CKBRD

EVEREADY BATTERY CO INC

25225 DETROIT ROAD
WESTLAKE, OH 44145
US

Emergency Phone: 440-835-7368

Info Phone: 440-835-7368

Cage: 66571

EVEREADY BATTERY CO INC

ST LOUIS, MO 63164 US

Telephone: 216-835-7368

Cage: 83740

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

1,2-DIMETHOXYETHANE

CAS: 110-71-4

RTECS: KI1451000

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

1,3-DIOXOLANE

CAS: 646-06-0

RTECS: JH6760000

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

GRAPHITE

CAS: 7782-42-5

RTECS: MD9659600

OSHA PEL see Table Z-3

ACGIH TLV: 2 MG/M3

LITHIUM OR LITHIUM ALLOY

CAS: 7439-93-2

RTECS: OJ5540000

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

LITHIUM PERCHLORATE

CAS: 7791-03-9

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

LITHIUM TRIFLUOROMETHANESULFONATE

CAS: 33454-82-9

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

LITHIUM TRIFLUOROMETHANESULFONIMIDE

CAS: 90076-65-6

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

MANGANESE DIOXIDE

CAS: 1313-13-9

RTECS: OP0350000

OSHA PEL C 5 MG/M3(AS MN)

ACGIH TLV: 0.2 MG/M3TWA(AS MN)

PROPYLENE CARBONATE

CAS: 108-32-7

RTECS: FF9650000

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:NO
Health Hazards Acute and Chronic:BATTERY IS HERMETICALLY SEALED. SHOULD
NOT BE OPENED OR BURNED. EXPOSURE TO INGEDIENTS OR COMBUSTION
PRODUCTS COULD BE HARMFUL. EYES: CONTENTS OF OPEN BATTERY CAN CAUSE
SEVERE IRRITATION AND CHEMICAL BURNS. SKIN: CONTENTS OF OPEN
BATTERY CAN CAUSE IRRITATION AND/OR CHEMICAL BURNS. SKIN
ABSORPTION: DIMETHOXYETHANE, DIOXOLANE, AND LITHIUM
TRIFLUOROMETHANESULFONATE MAY BE ABSORBED THROUGH SKIN, CAUSI NG
LOCALIZED INFLAMMATION. INHALATION: CONTENTS OF AN OPEN BATTERY CAN
CAUSE RESPIRATORY IRRITATION. INGESTION: SWALLOWING A BATTERY CAN
BE HARMFUL. CONTENTS OF AN OPEN BATTERY CAN CAUSE SERIOUS CHEMI CAL
BURNS OF MOUTH, ESOPHAGUS, GI TRACT.
Explanation of Carcinogenicity:UNDER NORMAL CONDITIONS OF USE , BATTERY
IS HERMETICALLY SEALED. CARBON BLACK INGEDIENT IS LISTED AS
POSSIBLE CARCINOGEN BY IARC. CARBON BLACK CAN BE CONTACTED ONLY IF
BATTERY IS OPENED.
Effects of Overexposure:UNDER NORMAL CONDITIONS OF USE, THE BATTERY IS
HERMETICALLY SEALED. CONTENTS OF OPEN BATTERY CAN CAUSE SERIOUS
CHEMICAL BURNS OF MOUTH, ESOPHAGUS, GI TRACT, IF INGESTED.
INHALATION: CONTENTS OF AN OPE N BATTERY CAN CAUSE RESPIRATORY
IRRITAITON. SKIN: CONTENTS CAN CAUSE INFLAMMATION. EYES: CONTENTS
OF OPEN BATTERY CAN CAUSE SEVERE IRRITATAION AND CHEMICAL BURNS.

First Aid:FIRST AID FOR EXPOSURE TO INGREDIENTS FROM BROKEN BATTERY:
INGESTION: IF BATTERY OR OPEN BATTERY IS INGESTED, DO NOT INDUCE
VOMITING OR GIVE FOOD AND DRINK. GET MEDICAL ATTENTION. CALL NAT'L
BATTERY I NGESTION HOTLINE, 202-625-.3333, FOR ADVICE. INHALATION:
MOVE TO FRESH AIR. GET MEDICAL ATTENTION. SKIN: REMOVE
CONTAIMINATED CLOTHING. WASH EXPOSED SKIN WITH SOAP AND WATER. IF A
CHEMICAL BURN OCCURS OR IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION. EYES: FLUSH EYES WITH WATER FOR 15 MIN. LIFTING UPPER
AND LOWER LIDS. GET MEDICAL ATTENTION.

Flash Point:NP
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:APPLY A SMOTHERING AGENT METL-X, SAND, DRY GROUND
DOLOMITE, SODA ASH, OR FLOOD THE AREA WITH WATER. A SMOTHERING
AGENT WILL EXTINGUISH BURNING LITHIUM BATTERIES.
Fire Fighting Procedures:WATER MAY NOT EXTINGUISH BURNING BATTERIES BUT
WILL COOL ADJACENT BATTERIES. BURNING BATTERIES WILL BURN
THEMSELVES OUT. FIRE FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING
APPARATUS. BURNING LITHIUM-M ANGANESE DIOXIDE BATTERIES PRODUCE
TOXIC AND CORROSIVE LITHIUM HYDROXIDE FUMES.
Unusual Fire/Explosion Hazard:VIRTUALLY ALL FIRES INVOLVING LITHIUM
BATTERIES CAN BE CONTROLLED WITH WATER, HOWEVER, HYDROGEN GAS MAY
BE EVOLVED. IN CONFINED SPACE, HYDROGEN GAS CAN FORM AN EXPLOSIVE
MIXTURE. IN THIS SITUATION, SM OTHERING AGENTS ARE RECOMMENDED.

Handling and Storage Precautions:STORE IN A COOL, WELL VENTILATED AREA.
ELEVATED TEMPERATURES CAN RESULT IN SHORTENED BATTERY LIFE
ACCIDENTAL SHORT CIRCUIT FOR A FEW SECONDS WILL NOT SERIOUSLY
AFFECT THE BATTERY. PROLONGED SHORT CIRC UIT WILL CAUSE THE BATTERY
TO LOSE ENERGY AND CAN CAUSE SAFETY RELEASE VENT TO OPEN.
Other Precautions:IF SOLDERING/WELDING TO BATTERY IS REQUIRED, CONSULT
YOUR EVEREADY BATTERY CO. REP. FOR PROPER PRECAUTIONS TO PREVENT
SEAL DAMAGE OR SHORT CIRCUIT. THIS BATTERY IS NOT DESIGNED TO BE
POTTED, ENCLOSED IN HERMETIC OVERPACKING, OR SEALED BY ANY MEANS
THAT PREVENTS FREE OPERATION OF THE DESIGNED SAFETY MECHANISMS.

Respiratory Protection:FIRE FIGHTERS SHOULD WEAR SELF-CONTAINED
BREATHING APPARATUS. RESPIRATORY PROTECTION IS NOT NECESSARY UNDER
NORMAL CONDITIONS.
Ventilation:NOT NECESSARY UNDER NORMAL CONDITIONS.
Protective Gloves:USE NEOPRENE OR NATURAL RUBBER GLOVES IF HANDLING AN
OPEN/LEAKING BATTERY.
Eye Protection:WEAR SAFETY GLASSES W/SIDE SHIELDS IF HANDLING
OPEN/LEAKING BATTERY.
Supplemental Safety and Health
THIS BATTERY IS MANUFACTURED IN A CHARGED STATE. IT IS NOT DESIGNED FOR
RECHARGING. RECHARGING CAN CAUSE BATTERY LEAKAGE OR, IN SOME CASES,
HIGH PRESSURE RUPTURE. INADVERTENT CHARGING CAN OCCUR IF A B ATTERY
IS INSTALLED BACKWARDS.

HCC:Z6
Appearance and Odor:2-CONTACT TERMINALS, 6-V, RECTANGULAR SHAPE, 17 MM
WIDE X 46 MM HIGH X34MM LONG

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, AND LOCAL REGULATIONS.

Toxicological Information:UNDER NORMAL CONDITIONS OF USE, THE BATTERY
IS HERMETRICALLY SEALED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:THE TRANSPORTATION OF LITHIUM BATTERIES IN THE
TYPES AND SIZES MANUFACTURED OR SOLD BY EVEREADY BATTERY CO IS NOT
REGULATED BY THE U.S. DEPARTMENT OF TRANSPORTATION OR THE MAJOR
INTERNATIONAL REGULATO RY BODIES. HOWEVER, TO MAINTAIN THIS
UNREGULATED STATUS, THE BATTERY MUST BE SEPARATED SO AS TO PREVENT
SHORT CIRCUITS AND BE PACKED IN STRONG OUTSIDE PACKAGING.

SARA Title III Information:AS AN ARTICLE, THIS BATTERY AND ITS CONTENTS
ARE NOT SUBJECT TO THE REQUIREMENTS OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT.